Instructions
Right-click on the "Bluetooth Symbol" in your taskbar.
Click "Add a Device."
Press the buttons on your Wiimote that say "1" and "2" at the same time. The lights on the Wiimote will begin blinking.
Watch the computer screen for your device to show up. It will come up as "Nintendo RVL-CNT-01."
Click "Next" and "Pair Without Using a Code." The PC will begin configuring your Wiimote. Click "Close" when this is complete.
Open your Dolphin program and choose the "Wiimote" button, choose "Real Remote" and click "OK." You are now ready to play your games with the Wiimote.