Things You'll Need
Instructions
Connect a standard PS3 controller to the PlayStation 3 via the provided USB data cable.
Power on the PS3 and wait for the red lights on top of the controller to flash.
Push the "PS" button in the middle of the controller to activate it.
Push the left directional button until you highlight the "Settings" option. Move down to "Accessory Settings" and select "Remote Control." This displays all the controls you have used on the PS3. Select the motion-sensor controller and choose "Delete." A prompt window appears, asking if you are sure you want to remove the synced device. Choose "Yes" to unsync the equipment.