Instructions
Investigate markings to see if there is a reference to "sterling" or "925," either of which would certify that the piece is made from sterling silver. There are also other informative markings, such as duty, city or standard marks. Silversmiths often use their own seals to identify their pieces. See the Resources section for a list of the most common marks.
Investigate the item for areas where the silver plating may have rubbed off. If it is an antique, you can see if the copper base is showing through on areas that have had a lot of wear. If the silver has a copper hue, it is probably silver-plated.
Take the items to a jeweler for a professional appraisal. Jewelers have acid tests that will show if the silver is genuine or if you have purchased a silver-plated object. The tests are not expensive, but you will have to weigh the cost against the value of the item in question.