Things You'll Need
Instructions
Look at the shape of the body. The exoskeleton of a centipede tends to be slightly flattened, while most species of millipede have a rounded exoskeleton.
Examine the head of the arthropod. Centipedes have long, segmented antennae, while millipedes have much shorter and thicker antennae if they are present at all.
Center on a body segment. Centipedes have a single set of legs per segment, while millipedes can have two or more pairs of legs per segment.
Look at the first segment on the arthropod's body. Centipedes have specialized -- usually longer or a different color -- legs along their first segment that produce venom to help kill prey. These modified legs are absent on millipedes, who spit venom on prey using specialized glands.