Sulfur Dioxide
The quantity of sulfur dioxide discharged from the copper smelting process depends on the makeup of the ore being refined. Complex ores may include lead, zinc, nickel and other metals. Total emissions from the process also depend on what methods are in place for capturing and converting the sulfur dioxide, typically ranging from less than 4 kilograms per metric ton (8 pounds per ton) of copper to 2,000 kilograms per metric ton (over 4,000 pounds per ton).
Particulate Matter Pollution
Particulate emissions can range from 0.1 kilograms per metric ton (0.2 pounds per ton) of copper to as high as 20 kilograms per metric ton (40 pounds per ton). The chief components of the particulate matter emitted by copper smelting are copper and iron oxides. Additional copper and iron compounds as well as ̶0;sulfides, sulfates, oxides, chlorides and/or fluorides of arsenic, antimony, cadmium, lead, mercury and zinc̶1; may also be in particulate matter emissions, according to the World Bank.
Waste Water
Waste water from copper smelting has dissolved and suspended solids that may include copper, lead, cadmium, zinc, arsenic and mercury -- as well as lime or aluminum oxides. Fluoride may also be in waste water, and the effluent may be slightly acidic. Negative water quality impacts are caused mainly by disposal practices that are not successful in containing wastes, run-on and runoff controls that are insufficient in preventing surface water from flowing through barriers or groundwater from infiltrating surface impediments.
Solid Waste
The smelting process typically produces less than 3 tons of solid waste per ton of copper produced. These solid wastes include sludges generated by sulfide precipitation (followed by sedimentation), sludges from acid plants and dusts from converters and furnaces. Volubility tests have shown that these wastes can leach toxic metals into the environment. The U.S. Environmental Protection Agency considers these wastes hazardous under the Resource Conservation and Recovery Act and the potential control costs feasible.