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Heat's Effect on Acids & Bases

The strength, or pH, of acids and bases is dependent upon many factors. One of those factors is temperature, which changes the concentration of acids and bases.
  1. Definitions

    • The Bronsted-Lowry definition of acids and bases states that an acid is anything that donates an H+, or positively charged hydrogen atom, and a base is anything that accepts an H+.

    Equilibrium

    • Weak acids only give up some H+ ions, and weak bases only accept some H+ ions. When the ratio between the products and the reactants is stable, equilibrium has been reached.

    Le Chatelier's Principle

    • Le Chatelier's principle says that if a system in equilibrium experiences a change, like a change in temperature, then the equilibrium of the system must change to compensate.

    Heat and Reversible Reactions

    • In reversible reactions, the products can spontaneously turn back into the reactants, as acids and bases can, and will have heat as either a product or a reactant. If heat is added, then the reaction will reach a new equilibrium favoring products if heat was a reactant, or reactants if heat was a product.

    Heat and Acids and Bases

    • Adding heat changes the equilibrium of an acid or base, altering the pH. Whether it will increase or decrease pH depends upon the individual reaction.


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