Instructions
Navigate to the Settings menu on your PlayStation 3.
Select "Accessory Settings," followed by "Calibrate Motion Controller."
Hold the Move controller you intend to calibrate. Press "X" on the Move controller.
Test your Move controller when prompted. This allows you to ensure your controller is working improperly before tweaking its set calibration.
Hold the controller as normal in one hand and hold the sphere at the tip with the other hand.
Move your controller 90 degrees counterclockwise when prompted by the console. This will occur three times.
Tilt the controller so the sphere points toward the ground when prompted. Tilt the controller so the sphere points toward the ceiling when prompted. The console will process the calibration automatically.