Instructions
Press the "Power" button on the front of the console to turn it on.
Plug the USB cable used to recharge PlayStation 3 controllers into a USB port on the front of the console. Plug the other end of the USB cable into the top of the PlayStation controller you want to synchronize with the console.
Press the "PS" button in the middle of the controller and wait for the lights along the top edge of your controller to flash. The controller is now synchronized with the console.