Things You'll Need
Instructions
Connect the cord of any USB webcam to the USB port located on the front of your console. If the camera has an indicator light, it should light up once you securely connect the camera to the PS3.
Start a video chat by scrolling to the "Friends" tab on the Xross Media Bar. Select the "Start a New Chat" option to enter the chat room.
Use the "Invite a Friend" option to send a chat invitation. Once your friend accepts your request, the video chat session will initialize. You can invite up to six people into any chat session.