Instructions
Automatic Method
Turn on the PS3.
Connect the PS3 controller to the PS3 using the supplied USB cable. The sync lights on the PS3 will flash.
Wait a few seconds for the pairing to take place automatically.
Manual Method
Turn on the PS3.
Connect the PS3 controller to the PS3 using the supplied USB cable.
Press the "PS" button in the middle of the controller. The light on the controller will flash. When it stabilizes, the sync has completed.