Instructions
Open the Windows 8 File Explorer and navigate to this folder on your Windows 8 hard drive: "C:\Users\User Name\My Documents\my games\skyrim\saves," where "User Name" is your Windows 8 account name.
Copy the save file using a flash drive, a cloud-based online storage service or any other file transfer method.
Paste the file in the following folder on the second computer: "C:\Users\User Name\My Documents\my games\skyrim\saves"
Launch Skyrim on the second computer and select "Load." The save file you copied from your previous Skyrim installation is available for you to load and play in the list of saved games.